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21.
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《Ceramics International》2020,46(13):21196-21201
In this work, TiO2/ZrO2 bilayer thin film was prepared on fluorine doped tin oxide (FTO)/glass substrates by using a simple and low-cost chemical solution deposition method. Reproducible bipolar resistive switching (RS) characteristics in Au/TiO2/ZrO2/FTO/glass devices are reported in this work. TiO2/ZrO2 bilayer thin films prepared in this work shows reversible bipolar resistive switching and unidirectional conduction performances under applying voltage and these special performances of TiO2/ZrO2 bilayer thin films was first reported. Obvious resistive switching performance can be observed after setting a compliance current, the ratio of high/low resistance reached about 100 at a read voltage of +0.1V and −0.1V and the RS properties showed no obvious degradation after 100 successive cycles tests. The resistive switching characteristics of Au/TiO2/ZrO2/FTO/glass device can be explained by electron trapping/detrapping related with the vacancy oxygen defects in TiO2/ZrO2 bilayer thin film layer. According to slope fitting, the main conduction mechanisms of the sample are Ohmic and Space charge limited current mechanism. 相似文献
23.
2002年12月国务院批复了《南水北调工程总体规划》,明确中线工程分两期建设。目前,一期工程已经通水。近年来,随着社会经济的快速发展,受水区的人口、生产规模、节水水平、人们对环境的要求都发生了变化,因此有必要根据新的情况对受水区的用水需求重新预测。分析了城市化发展和城镇用水变化的新形势,依据流域、区域水资源规划成果,提出了中线二期工程受水区需调水量,并与《南水北调中线工程规划》提出的二期需调水量进行对比,以供各方参考。 相似文献
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社会经济快速发展,科学技术不断进步,针对我国现代工业化工行业发展,所产生的新型化工技术应用,促进我国化工生产效率的提升。工业的发展不可避免地会带来污染物的产生,如果不能有效控制化工排放污染物,温室效应问题会更加严重。本文对绿色化工技术在精细化工中的有效应用进行研究,降低工业废气污染物排放量,维护生态环境平衡。 相似文献
26.
以柠条为原料,分析了其化学组分和纤维形态,并探讨了柠条双螺杆CMP法的制浆工艺以及浆料的纤维形态和成纸的物理性能。研究结果表明:与针、阔叶木相比,柠条原料中纤维素和综纤维素质量分数较低,苯醇抽出物和热水抽出物质量分数较高,柠条纤维长度总体偏短,木质部和皮部的纤维质量平均长度分别为0.621和0.819 mm,还存在部分杂细胞。采用3.5% Na2SO3和1.5% NaOH常温预浸12 h、90℃汽蒸1 h后再用双螺杆挤浆机在质量分数35%下进行搓丝,并结合高浓盘磨机磨浆,所得CMP浆得率可达73%。柠条CMP浆基本保持了纤维原有的长度,质量平均长度达0.650 mm,长宽比为32.7,纤维解离较好,但分丝帚化情况不理想,含有部分纤维束和杂细胞。当加拿大游离度为300 mL时,柠条CMP浆成纸的环压强度指数和松厚度较高,分别为8.67(N·m)/g和2.56 cm3/g,抗张指数为19.6(N·m)/g,本色浆白度较高,达50%(ISO)。柠条CMP浆适合配抄瓦楞原纸等包装用纸,漂白后可配抄新闻纸和白板纸。 相似文献
27.
Dr. Jiayao Y. Wang Dr. Jiaqi Q. Li Prof. Dr. Yumei M. Xiao Prof. Dr. Bin Fu Prof. Dr. Zhaohai H. Qin 《ChemMedChem》2020,15(5):404-410
Mitochondrial oxidative damage and dysfunction contribute to a wide range of human diseases. Considering the limitation of conventional antioxidants and that mitochondria are the main source of reactive oxygen species (ROS) which induce oxidative damage, mitochondria-targeted antioxidants which can selectively block mitochondrial oxidative damage and prevent various types of cell death have been widely developed. As a lipophilic cation, triphenylphosphonium (TPP) has been commonly used in designing mitochondria-targeted antioxidants. Conjugated with the TPP moiety, antioxidants can achieve more than 1000-fold higher mitochondrial concentration depending on cell membrane potentials and mitochondrial membrane potentials. Herein we discuss the deficiencies of conventional antioxidants and the advantages of mitochondrial targeting, and review various types of TPP-based mitochondria-targeted antioxidants. These provide theoretical and background support for the design of new anti-oxidant. 相似文献
28.
Textured surface is commonly used to enhance the efficiency of silicon solar cells by reducing the overall reflectance and improving the light scattering. In this study, a comparison between isotropic and anisotropic etching methods was investigated. The deep funnel shaped structures with high aspect ratio are proposed for better light trapping with low reflectance in crystalline silicon solar cells. The anisotropic metal assisted chemical etching (MACE) was used to form the funnel shaped structures with various aspect ratios. The funnel shaped structures showed an average reflectance of 14.75% while it was 15.77% for the pillar shaped structures. The average reflectance was further reduced to 9.49% using deep funnel shaped structures with an aspect ratio of 1:1.18. The deep funnel shaped structures with high aspect ratios can be employed for high performance of crystalline silicon solar cells. 相似文献
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30.
Wang Hay Kan Chenxi Wei Dongchang Chen Tao Bo Bao‐Tian Wang Yan Zhang Yangchao Tian Jun‐Sik Lee Yijin Liu Guoying Chen 《Advanced functional materials》2019,29(17)
Lithium‐rich disordered rock‐salt oxides have attracted great interest owing to their promising performance as Li‐ion battery cathodes. While experimental and theoretical efforts are critical in advancing this class of materials, a fundamental understanding of key property changes upon Li extraction is largely missing. In the present study, single‐crystal synthesis of a new disordered rock‐salt cathode material, Li1.3Ta0.3Mn0.4O2 (LTMO), and its use as a model compound to investigate Li concentration–driven evolution of local cationic ordering, charge compensation, and chemical distribution are reported. Through the combined use of 2D and 3D X‐ray nanotomography, it is shown that Li removal accompanied by oxygen oxidation is correlated with the development of morphological defects such as particle cracking. Chemical heterogeneity, quantified by subparticle level distribution of Mn valence state, is minimal during Mn redox, which drastically increases upon the formation of cracks during oxygen redox. Density functional theory and bond valence sum mismatch calculations reveal the presence of local short‐range ordering in the pristine oxide, which gradually disappears along with the extraction of Li. The study suggests that with cycling the transformation into true cation–disordered state can be expected, which likely impacts the voltage profile and obtainable energy density of the oxide cathodes. 相似文献